Copied from: http://lordcalls.com/prayers-to-saints/nine-day-novena-to-st-ann
First Day
Glorious St. Ann, filled with compassion for those who invoke you, with love for those who suffer, heavily laden with the weight of my 
troubles, I knee at your feet and humbly beg you to take my present need under your special protection. (mention your request).
Vouchsafe to recommend it to your daughter, the Blessed Virgin Mary, and lay it before the throne of Jesus. Cease not to intercede for me until my request is granted. Above all, obtain for me the grace to one day meet God face to face, and with you and Mary and all the angels and saints praising Him through all eternity. Amen.
Pray for us, Saint Anne. That we may be made worthy of the promises of Christ.
O Jesus, Holy Mary, St. Ann, help me now and at the hour of my death. Good St. Ann, intercede for me.
Day 1 Novena Prayer
Dear St. Ann, though I am but a prodigal child, I appeal to you and place myself under your great motherly care. Please listen to my prayers and grant my requests. See my contrite heart, and show me your unfailing goodness. Deign to be my advocate and recommend me to God’s infinite mercy. Obtain for me forgiveness of my sins and the strength to begin a new life that will last forever. Blessed St. Ann, I also beg of you the grace to love, to serve, and to honor your daughter, the most holy Virgin Mary. Please recommend me to her and pray to her for me. She refuses none of your requests but welcomes with loving kindness all those for whom you intercede. Good Jesus, be merciful to the faithful servants of Your grandmother St. Ann.
Great Saint Anne, engrave indelibly on my heart and in my mind the words that have reclaimed and sanctified so many sinners: “What shall it profit a man to gain the whole world if he lose his own soul?” May this be the principle fruit of these prayers by which I will strive to honor you during this novena. At your feet renew my resolution to invoke you daily, not only for the success of my temporal affairs and to be preserved from sickness and suffering, but above all, that I may be preserved from all sin and that I may succeed in working out my eternal salvation and that I will receive the special grace of (mention your request). O most powerful Saint Anne, do not let me lose my soul, but obtain for me the grace of winning my way to heaven, there with you, you blessed spouse, and your glorious daughter, to sing the praise of the most holy and adorable Trinity forever and ever. Amen.